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Metallic graphene nanoribbons (GNRs) represent a critical component in the toolbox of low-dimensional functional materials technolo-gy serving as 1D interconnects capable of both electronic and quantum information transport. The structural constraints imposed by on-surface bottom-up GNR synthesis protocols along with the limited control over orientation and sequence of asymmetric monomer building blocks during the radical step-growth polymerization has plagued the design and assembly of metallic GNRs. Here we report the regioregular synthesis of GNRs hosting robust metallic states by embedding a symmetric zero-mode superlattice along the backbone of a GNR. Tight-binding electronic structure models predict a strong nearest-neighbor electron hopping interaction between adjacent zero-mode states resulting in a dispersive metallic band. First principles DFT-LDA calculations confirm this prediction and the robust, metallic zero-mode band of olympicene GNRs (oGNRs) is experimentally corroborated by scanning tunneling spectroscopy.more » « less
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Mutlu, Zafer; Jacobse, Peter H.; McCurdy, Ryan D.; Llinas, Juan P.; Lin, Yuxuan; Veber, Gregory C.; Fischer, Felix R.; Crommie, Michael F.; Bokor, Jeffrey (, Advanced Functional Materials)
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McCurdy, Ryan D.; Jacobse, Peter H.; Piskun, Ilya; Veber, Gregory C.; Rizzo, Daniel J.; Zuzak, Rafal; Mutlu, Zafer; Bokor, Jeffrey; Crommie, Michael F.; Fischer, Felix R. (, Journal of the American Chemical Society)null (Ed.)
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